hi,
Causes can be skin infection(bacterial or fungal) lead to replicate themselves and create bad odour,some times genetic or bad hygiene.
Most excess sweating is due to excess sweat glands or their hyper stimulation.
Here are some tips to stop this odour.
1) If your husband has 
eczema or 
dermatitis or 
allergy then first take proper antibiotics or anti fungal as per your 
dermatologist opinion.
2).Always take balanced diet and drink plenty of water daily. 
3) Avoid tight fitting clothes rather wear loose clothes.
4) Wear cotton material clothes and avoid synthetic silk.
5) Bath with antibacterial soap like 
dettol,savlon
6) Always clean armpits,twice or thrice with brush during bathing.
7) Use antiperspirants and deodarants together like aluminium chlorhydrate or zirconium,one will block perspiration and other will mask the smell.
8) Use antibacterial creams or hand sanitizers on armpits.
10) Curtailing excess tea or coffee.